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Bringing pH down

It's freezing in Norway today, even some snow :)

Anyway, I have this old book - which holds formulas & stuff, related to chemistry.
It's WAY to long since I learned this stuff - so I cannot advise on this topic - but a thought occured when seeing the list of acids...

These look interesting:
H2CO3 and HNO3 / HNO2.

Can't these acids be used in a constructive way to bring pH down, AND get some additional interesting effects...
What would these effect be...
Are they impossible to aquire or store etc etc..

Just an idea.