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dosing PMDD



I've been dosing Sears-Collin formula PMDD at 6ml a day in a 65 gallon
with about 59 gallons of water in it for 2 months.  Plant growth is very
good and I change about 20+ gallons of water a week.  Does that seem
reasonable?
I have recently bought some new fish - Aulonocara sp. and Labidochromis -
and some of them scratch their gills occasionally by rubbing against
stuff.  Is it possible that this rubbing has something to do with PMDD?
Any ideas about what to do?  Thanks - CCI.