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Substrate Ammonia smell

I am in the process of tearing down my tank that had the problem with plants dying. I decided that there must be something in the sand that was leaching in the water and killing the plants. This is a sand over kitty litter tank with Osmocote time release Fertilizer in the litter.
As I got past the sand and into the kitty litter there is a distinct smell of ammonia. This isn't normal is it? Any ideas as to why?
Jeff <*\\><
Mt. 4:19 And he saith unto them, Follow me,
and I will make you fishers of men.