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[APD] a newbie in need

I recently added a dose of iron supplement to my small five-gallon aquarium, 
and in the same day changed the liquid in my co2 reactor which upped co2 
production. The next day, i found that one of the guppies living in this 
tank is now crashed on the gravel bed, tail and dorsal fins clamped. The 
other guppies seem fine. i'm concerned this was either caused by an iron 
overdose, or the drop in pH caused by increased co2 production. which might 
it be, and what can i do? I've changed about a quarter of the water and 
added some aquarium salt, no visible improvement yet. Help!

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